【B级文件中文翻译完整版】《科学》(20260806出版)一周论文导读 为深入了解这种多功能性
内容摘要
编译|未玖物理学PhysicsLevitated sensor for magnetometry in ambient environment磁悬浮传感器助力环境条件下的磁力测量▲ 作者:Wei Ji
▲ Abstract:

Hurricane evolution is 出版affected by turbulence in the hurricane boundary layer (HBL), which is typically measured using aircraft flights and towers. Through a case study of a landfalling hurricane, we show that seismoacoustic data can also be used for HBL turbulence analysis. We identified contributions of HBL turbulence in infrasound pressure and seismic displacement, validating our interpretation by combining large-eddy simulation, calibrated with meteorological data, with quasi-static elastic deformation modeling. The convection velocity of the turbulent pressure field is key to this pressure–displacement coupling. For atmospheric studies, continuous infrasound pressure serves as a proxy for 10-meter wind speed, and the inertial subrange of pressure spectra provides an estimate of the turbulent dissipation rate near the top of the surface layer at ~100 to 200 meters, complementing portable tower data at ~10 meters.


▲ Abstract:
In organic chemistry,科学 functionalization of two adjacent carbons often starts from alkenes or already disubstituted precursors. Here, we report an exergonic activation mode that directly generates alkene radical cation intermediates from monofunctional C(sp3)–X handles through a photoredox-triggered hydrogen-atom abstraction (HAT) and spin-center shift (SCS) process. Computations show that electron delocalization and a network of hydrogen-bonding solvent molecules facilitate a concerted [HAT+SCS] mechanism. The catalytic platform was used to design a transfer of electrophilic reactivity (C–X) from one carbon to another, which we refer to as electrophilic shuttling. Thus, two nucleophiles can be used in the construction of 1,2-difunctionalization adducts from homobenzylic C–X synthons, delivering bisazole architectures and demonstrating compatibility with other nucleophile classes. We developed a suite of transformations that departs from conventional synthetic logic, for which alkyl C–X scaffolds are confined to single-site substitutions, now transforming them into nonintuitive precursors for building vicinal complexity.
地球科学Earth Science
The climate benefits of retiring a fully operational internal combustion engine vehicle
放弃功能完好内燃机汽车的气候效益
▲ 作者